Murata, Takumi’s team published research in Green Chemistry in 2022 | CAS: 5961-59-1

Green Chemistry published new progress about Methylation. 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Application of 4-Methoxy-N-methylaniline.

Murata, Takumi published the artcileDeoxygenative CO2 conversions with triphenylborane and phenylsilane in the presence of secondary amines or nitrogen-containing aromatics, Application of 4-Methoxy-N-methylaniline, the main research area is secondary amine indole deoxygenative methylation triphenylborane catalyst.

BPh3 catalyzed the N-methylation of secondary amines and the C-methylenation (methylene-bridge formation between aromatic rings) of N,N-dimethylanilines or 1-methylindoles in the presence of CO2 (1 atm) and PhSiH3 without solvent at 30-40 °C. A cascade reaction from 1-methyl-2-oxindole to 3,3â€?methylenebis(1-methylindole) via 1-methylindole also proceeded.

Green Chemistry published new progress about Methylation. 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Application of 4-Methoxy-N-methylaniline.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem