Hamilton, Joseph Z.’s team published research in Tetrahedron Letters in 2015-11-25 | CAS: 21834-92-4

Tetrahedron Letters published new progress about Divinyl ketones Role: RCT (Reactant), RACT (Reactant or Reagent). 21834-92-4 belongs to class isoquinoline, name is 5-Methyl-2-phenylhex-2-enal, and the molecular formula is C13H16O, Computed Properties of 21834-92-4.

Hamilton, Joseph Z. published the artcileHydroxylamine catalyzed Nazarov cyclizations of divinyl ketones, Computed Properties of 21834-92-4, the main research area is divinyl ketone Nazarov cyclization hydroxylamine catalyst.

The first examples of iminium catalyzed Nazarov cyclizations of divinyl ketones are presented. Experiments describing hydroxylamine catalysis of the cyclization of eight α-alkoxy divinyl ketones (60-79% yield) and one unactivated divinyl ketone (38% yield) are reported. Ph substitution at the β-position of the divinyl ketone inhibits cyclization, whereas β-alkyl substituted α-alkoxy divinyl ketones readily cyclize.

Tetrahedron Letters published new progress about Divinyl ketones Role: RCT (Reactant), RACT (Reactant or Reagent). 21834-92-4 belongs to class isoquinoline, name is 5-Methyl-2-phenylhex-2-enal, and the molecular formula is C13H16O, Computed Properties of 21834-92-4.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem