Xin, Zhuo published the artcileRu-Catalyzed Switchable N-Hydroxyethylation and N-Acetonylation with Crude Glycerol, Category: isoquinoline, the main research area is beta amino alc regioselective preparation; amine polyol hydroxyethylation ruthenium catalyst; ketone beta amino regioselective preparation; polyol amine acetonylation ruthenium catalyst; acetonylation; hydrogen borrowing; hydroxyethylation; polyalcohol; switchable selectivity.
Highly efficient Ru-catalyzed selective C-C or C-O bond cleavage of polyols (e.g., crude glycerol) for N-hydroxyethylation or N-acetonylation of amines to give β-amino alcs. RR1N(CH2)2OH [R = Ph, 2-MeC6H4, 4-ClC6H4, etc.; R1 = Me, Et, Bn, etc.] and β-amino ketones ArNR2CH2C(O)Me [Ar = Ph, 2-MeC6H4, 4-BrC6H4, etc.; R2 = Me, Bn, etc.] in moderate-to-excellent yields was achieved through the hydrogen-borrowing approach. The use of new redox-active catalysts containing bisphosphine/thienylmethylamine ligands allowed this hydrogen-borrowing system to be operated selectively under both basic and acidic conditions.
ChemSusChem published new progress about Acetylation. 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Category: isoquinoline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem