Li, Xiao-Ya published the artcileDesign of Lewis base functionalized ionic liquids for the N-formylation of amines with CO2 and hydrosilane: The cation effects, Synthetic Route of 5961-59-1, the main research area is recyclable ionic liquid preparation; amine carbon dioxide hydrosilane ionic liquid formylation green chem; formamide preparation.
A series of functionalized ionic liquids (ILs) were developed for the reductive functionalization of CO2 with amine and hydrosilane to afford formamides under mild conditions. It was found that 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-based IL i.e. [DBUC12]Br showed high efficiency for the N-formylation reaction of amines without using any organic solvents or additives. Furthermore, control experiments suggested the cations with active hydrogen may weaken the nucleophilicity of anions through ion pairing interactions, thereby affecting the activation of hydrosilane. The reaction mechanism was then investigated by D. Functional Theory (DFT) calculations This protocol represented a highly efficient and environmentally friendly example for catalytic conversion of CO2 into value-added chems. such as formamide derivatives by employing DBU functionalized ILs.
Catalysis Today published new progress about Formamides Role: SPN (Synthetic Preparation), PREP (Preparation). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Synthetic Route of 5961-59-1.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem