Yasukawa, Naoki published the artcileGold-Catalyzed Tandem Oxidative Coupling Reaction between β-Ketoallenes and Electron-Rich Arenes to 2-Furylmethylarenes, Product Details of C8H10O2, the main research area is furylmethylarene preparation; ketoallene arene tandem oxidative coupling reaction gold catalyst.
A tandem oxidative coupling reaction of β-ketoallenes R1C(O)CH(R2)CH=C=CH2 (R1 = Ph, n-nonyl, 2-methoxyphenyl, etc.; R2 = H, n-pentyl; R1R2 = -(CH2)4-) and arenes ArH (Ar = 2,4,6-triemthoxyphenyl, 1H-indol-3-yl, 2-methoxy-9-methyl-9H-carbazol-3-yl, etc.) was developed, which leads to the formation of 2-furylmethylarenes I using AuCl3 and phenyliodine diacetate. The AuIII salt catalyzed the cyclization of β-ketoallenes to form a 2-furylmethyl gold intermediate, and the subsequent C-H functionalization of arenes proceeded smoothly. During the oxidative coupling, nucleophilic additions occurred at the center and terminal carbon atoms of the allene moiety to form C-O and C-C bonds.
Organic Letters published new progress about Allenes Role: RCT (Reactant), RACT (Reactant or Reagent) (keto). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Product Details of C8H10O2.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem