Mondal, Atanu published the artcilePhosphine-Catalyzed Intramolecular Vinylogous Aldol Reaction of α-Substituted Enones, Related Products of isoquinoline, the main research area is indenone preparation diastereoselective; substituted enone intramol aldol phosphine catalyst.
The first phosphine-catalyzed intramol. vinylogous aldol reaction (IVAR) of α-substituted enones was demonstrated. This strategy provided access to various pentannulated (hetero)arenes and dibenzocycloheptanones incorporated with two contiguous stereocenters, one of which is an all-carbon quaternary center. The scope of this work was further broadened through elaborations of the IVAR adducts to (i) benzannulated nine-membered carbocyclic systems, (ii) interesting classes of 1,3-dienes, 1,3,5-trienes, and 1-yn-3,5-dienes, and (iii) the analogs of echinolactone D and russujaponol F.
Organic Letters published new progress about Aldol condensation catalysts, stereoselective. 21834-92-4 belongs to class isoquinoline, name is 5-Methyl-2-phenylhex-2-enal, and the molecular formula is C13H16O, Related Products of isoquinoline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem