Stephens, Thomas C. published the artcileTransition-Metal-Free Homologative Cross-Coupling of Aldehydes and Ketones with Geminal Bis(boron) Compounds, Synthetic Route of 1205-17-0, the main research area is transition metal free homologative cross coupling aldehyde ketone; geminal bis boron compound homologative cross coupling aldehyde ketone; homologated carbonyl compound preparation.
Authors report a transition-metal-free coupling of aldehydes and ketones with geminal bis(boron) building blocks which provides the coupled, homologated carbonyl compound upon oxidation This reaction not only extends an alkyl chain containing a carbonyl group, it also simultaneously introduces a new carbonyl substituent. Authors also demonstrated that enantiopure aldehydes with an enolizable stereogenic center undergo this reaction with complete retention of stereochem.
Organic Letters published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Synthetic Route of 1205-17-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem